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A 2017 study by Wischik et al

Reduce Toxin Exposure: Since glutathione is the bodys primary detoxifier, reducing your exposure to environmental toxins (like heavy fragrances, harsh cleaning chemicals, or secondhand smoke) allows your body to use its glutathione for cellular protection rather than processing external pollutants

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Generation of water-ice crystals at a containers periphery (where heat transfer is greatest) can produce a salting out effect, whereby the protein and excipients become increasingly concentrated at the slower-freezing center of a container (21)