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In addition to extracellular catabolism, intracellular GSH degradation is mediated by the ChaC GSH specific gamma-glutamylcyclotransferase family (CHAC1 and CHAC2), which cleaves GSH into 5-oxoproline and Cys-Gly 28,29

These melanogenesis studies have used MT-II as a high-potency reference agonist for establishing the upper limits of pharmacologically achievable melanogenesis through MC1R activation

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